Synthesis and characterisation of novel metal-organic frameworks (MOFs) based on zirconium and bicinchoninic acid

Albayati, N.; AL-dulaimy, W.; Jweeg, M.; Kadhom, M.; Salih, S.; Abdullah, G.

Growing Science » Current Chemistry Letters » Synthesis and characterisation of novel metal-organic frameworks (MOFs) based on zirconium and bicinchoninic acid

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print) Quarterly Publication Volume 13 Issue 1 pp. 41-48 , 2024

Synthesis and characterisation of novel metal-organic frameworks (MOFs) based on zirconium and bicinchoninic acid Pages 41-48 Download PDF

Authors: Noor Albayati, Waseem Yousif M. AL-dulaimy, Muhsin J Jweeg, Mohammed Kadhom, Suhaib Salih, Ghassan Abdullah

DOI: 10.5267/j.ccl.2023.9.001

Keywords: MOFs, Zr-Bads, Nanoparticles, Nanotechnology, Solvothermal

Abstract: Metal-organic frameworks (MOFs) are a relatively new class of materials of unique porous structures and exceptional properties. Currently, more than 110,000 types of MOFs have been reported among the countless possibilities. In this study, we have synthesised a novel MOF using zirconium chloride as the metal source and 4,4'-dicarboxy-2,2'-biquinoline (bicinchoninic acid disodium salt) as the linker, which reacted in N,N-Dimethylformamide (DMF) solvent. Three preparation methods were employed to prepare five types of the MOF, and they were compared to optimize the synthesis conditions. The resulting MOFs, named Zr-BADS, were characterised using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), microscopy, and X-ray diffraction (XRD). By incorporating methanol into the preparation solvent, the surface area was increased to 396 m2/g. Additionally, the prepared MOFs exhibited amorphous shapes, with variations in size depending on the synthesis method. This research demonstrates the significance of the preparation method in controlling resulting particles’ properties.

How to cite this paper

 Albayati, N., AL-dulaimy, W., Jweeg, M., Kadhom, M., Salih, S & Abdullah, G. (2024). Synthesis and characterisation of novel metal-organic frameworks (MOFs) based on zirconium and bicinchoninic acid.Current Chemistry Letters, 13(1), 41-48.

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