Removal of Zn, Pb, and Ni heavy metals from aqueous system using efficient modified-banana peel adsorbent

Gahlan, A.; Hosny, S.; Fathi, A.; Fargaly, O.

Growing Science » Current Chemistry Letters » Removal of Zn, Pb, and Ni heavy metals from aqueous system using efficient modified-banana peel adsorbent

Journals

CCL Volumes

Volume 1 (23)
- Issue 1 (7)
- Issue 2 (5)
- Issue 3 (6)
- Issue 4 (5)

Volume 2 (26)
- Issue 1 (7)
- Issue 2 (6)
- Issue 3 (6)
- Issue 4 (7)

Volume 3 (30)
- Issue 1 (7)
- Issue 2 (10)
- Issue 3 (8)
- Issue 4 (5)

Volume 4 (21)
- Issue 1 (5)
- Issue 2 (5)
- Issue 3 (6)
- Issue 4 (5)

Volume 5 (20)
- Issue 1 (5)
- Issue 2 (5)
- Issue 3 (5)
- Issue 4 (5)

Volume 6 (20)
- Issue 1 (5)
- Issue 2 (5)
- Issue 3 (5)
- Issue 4 (5)

Volume 7 (15)
- Issue 1 (4)
- Issue 2 (4)
- Issue 3 (4)
- Issue 4 (3)

Volume 8 (20)
- Issue 1 (5)
- Issue 2 (5)
- Issue 3 (5)
- Issue 4 (5)

Volume 9 (20)
- Issue 1 (5)
- Issue 2 (5)
- Issue 3 (5)
- Issue 4 (5)

Volume 10 (43)
- Issue 1 (5)
- Issue 2 (7)
- Issue 3 (17)
- Issue 4 (14)

Volume 11 (43)
- Issue 1 (14)
- Issue 2 (11)
- Issue 3 (10)
- Issue 4 (8)

Volume 12 (78)
- Issue 1 (21)
- Issue 2 (22)
- Issue 3 (20)
- Issue 4 (15)

Volume 13 (68)
- Issue 1 (23)
- Issue 2 (17)
- Issue 3 (16)
- Issue 4 (12)

Countries

Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print) Quarterly Publication Volume 12 Issue 1 pp. 45-54 , 2023

Removal of Zn, Pb, and Ni heavy metals from aqueous system using efficient modified-banana peel adsorbent Pages 45-54 Download PDF

Authors: Ahmed. A. Gahlan, Shimaa Hosny, Ahmed Fathi, O. A. Fargaly

DOI: 10.5267/j.ccl.2022.9.007

Keywords: Banana peel, Heavy metals, Adsorption, Waste water, Agricultural waste

Abstract: Heavy metals contamination of water is a serious and complex environmental problem due to rapid industrialization, bioaccumulation and non-degradability. Therefore, the reuse of agricultural waste in the process of purifying water from pollutants is an attractive and promising method. Almost inexpensive materials are used to purify water, thus achieving the desired economic and environmental goal. In this study banana peel (BP) was used before and after modification by 0.1M sulphuric acid (H2SO4) to enhance the removal of Zinc Zn(II), Lead Pb(II) and Nickel Ni(II). The effect of various parameters was studied Such as pH, contact time, adsorbent dosage and initial metal ion concentration at 5 ppm. All these parameters were studied in batch experiments for a comparative study. The removal percentage was found to be 84% Zn (II),78%Pb (II) and 72% Ni (II) before modification and 92% Zn (II) , 94% Pb (II) and 96% Ni (II) after modification at initial concentration of 5 ppm. The data obtained from sorption isotherms were described with Langmuir and Freundlich isotherm models but were found to be well fitted for the Langmuir model. The correlation coefficient values R2 for Langmuir were at the range (0.996-0.999) while that for Freundlich were at the range (0.912-0.972). The rate of adsorption follows Pseudo-second-order kinetics. This work proved the high banana peels efficiency as an adsorbent agent for heavy metals removal from aqueous solutions.

How to cite this paper

 Gahlan, A., Hosny, S., Fathi, A & Fargaly, O. (2023). Removal of Zn, Pb, and Ni heavy metals from aqueous system using efficient modified-banana peel adsorbent.Current Chemistry Letters, 12(1), 45-54.

Refrences

1. Ngah W. W., and Hanafiah M. M. (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresour. Technol., 99 (10) 3935-3948.
2. Organization W. H., and WHO. (2004) Guidelines for drinking-water quality, 4th Ed, world health organization.
3. Kadirvelu K., Thamaraiselvi K., and Namasivayam C. (2001) Removal of heavy metals from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste. Bioresour. Technol., 76 (1) 63-65.
4. Williams C., Aderhold D., and Edyvean R. (1998) Comparison between biosorbents for the removal of metal ions from aqueous solutions. Water Res., 32 (1) 216-224.
5. Gunatilake S. (2015) Methods of removing heavy metals from industrial wastewater. Methods, 1 (1) 14.
6. Reza M. S., Yun C. S., Afroze S., Radenahmad N., Bakar M. S. A., Saidur R., Taweekun J., and Azad A. K. (2020) Preparation of activated carbon from biomass and its’ applications in water and gas purification, a review. Arab J. Basic Appl. Sci., 27 (1) 208-238.
7. Ali S. H., Emran M. Y., and Gomaa H. (2021) Rice husk-derived nanomaterials for potential applications, in: ed.^(Eds). Waste recycling technologies for nanomaterials manufacturing. Springer, 541-588.
8. Aksu Z. (2005) Application of biosorption for the removal of organic pollutants: a review. Process Biochem., 40 (3-4) 997-1026.
9. Vardhan K. H., Kumar P. S., and Panda R. C. (2019) A review on heavy metal pollution, toxicity and remedial measures: Current trends and future perspectives. J. Mol. Liq., 290 111197.
10. Karunasagar D., Krishna M. B., Rao S., and Arunachalam J. (2005) Removal and preconcentration of inorganic and methyl mercury from aqueous media using a sorbent prepared from the plant Coriandrum sativum. J. Hazard. Mater., 118 (1-3) 133-139.
11. Johnson P., Watson M., Brown J., and Jefcoat I. (2002) Peanut hull pellets as a single use sorbent for the capture of Cu (II) from wastewater. J. Waste Manag., 22 (5) 471-480.
12. Adesanmi A., Evuti A., Aladeitan Y., and Abba A. (2020) Utilization of waste in solving environmental problem: Application of banana and orange peels for the removal of lead (II) ions from aqueous solution of lead nitrate. Niger. J. Sci. Technol., 6 (1) 18-33.
13. Negi A., Negi A., Kumar R., Kumar B., Kumar Joshi S., and Singh Bhandari N. (2021) Harmful Impacts of Heavy Metals and Utility of Biosorption Technique for Their Removal from Wastewater: A Review. J. Chem. En. Sci. A., 8 (1) 1-17.
14. Kumar J., Balomajumder C., and Mondal P. (2011) Application of Agro‐Based Biomasses for Zinc Removal from Wastewater–A Review. CLEAN–Soil, Air, Water, 39 (7) 641-652.
15. Nguyen T., Ngo H., Guo W., Zhang J., Liang S., Yue Q., Li Q., and Nguyen T. (2013) Applicability of agricultural waste and by-products for adsorptive removal of heavy metals from wastewater. Bioresour. Technol., 148 574-585.
16. Acharya J., Kumar U., and Rafi P. M. (2018) Removal of heavy metal ions from wastewater by chemically modified agricultural waste material as potential adsorbent-a review. Int. J. Eng. Technol., 8 (3) 526-530.
17. Nakajima A., and Sakaguchi T. (1990) Recovery and removal of uranium by using plant wastes. Biomass, 21 (1) 55-63.
18. Duru C., Duru I., Ogbonna C., Enedoh M., and Emele P. (2019) Adsorption of copper ions from aqueous solution onto natural and pretreated maize husk: adsorption efficiency and kinetic studies. J. Chem Soc. Nigeria, 44 (5) 798 -803.
19. Thirumavalavan M., Lai Y.-L., Lin L.-C., and Lee J.-F. (2010) Cellulose-based native and surface modified fruit peels for the adsorption of heavy metal ions from aqueous solution: Langmuir adsorption isotherms. J. Chem. Eng. Data, 55 (3) 1186-1192.
20. Deshmukh P. D., Khadse G. K., Shinde V. M., and Labhasetwar P. (2017) Cadmium removal from aqueous solutions using dried banana peels as an adsorbent: kinetics and equilibrium modeling. J. bioremediat. biodegrad., 8 (03) 1-7.
21. Farooq U., Khan M. A., Athar M., and Kozinski J. A. (2011) Effect of modification of environmentally friendly biosorbent wheat (Triticum aestivum) on the biosorptive removal of cadmium (II) ions from aqueous solution. J. Chem. Eng., 171 (2) 400-410.
22. Alkaff A., Hendri H., Farozy I., Annisa M., and Aritonang R. (2018) Use of Eichhornia crassipes modified Nano-chitosan as a biosorbent for lead (II), cadmium (II), and copper (II) ion removal from aqueous solutions. in IOP Conference Series: Materials Science and Engineering, 299 (1) 012003.
23. Ahmed S. A., El-Roudi A. M., and Salem A. A. (2015) Removal of Mn (II) from ground water by solid wastes of sugar industry. J. Environ. Sci. Technol., 8 (6) 338.
24. Lamelas C., Avaltroni F., Benedetti M., Wilkinson K. J., and Slaveykova V. I. (2005) Quantifying Pb and Cd complexation by alginates and the role of metal binding on macromolecular aggregation. Biomacromolecules, 6 (5) 2756-2764.
25. Pardo R., Herguedas M., Barrado E., and Vega M. (2003) Biosorption of cadmium, copper, lead and zinc by inactive biomass of Pseudomonas putida. Anal. Bioanal. Chem., 376 (1) 26-32.
26. Jawad A. H., Rashid R. A., Ishak M. A. M., and Ismail K. (2018) Adsorptive removal of methylene blue by chemically treated cellulosic waste banana (Musa sapientum) peels. J. Taibah Univ. Sci., 12 (6) 809-819.
27. Hosny S., Gouda G. A., and Abu‐El‐Wafa S. M. (2022) Novel Nano Copper Complexes of a New Schiff Base: Green Synthesis, a New Series of Solid Cr (II), Co (II), Cu (II), Pd (II) and Cd (II) Chelates, Characterization, DFT, DNA, Antitumor and Molecular Docking Studies. Appl. Organomet. Chem., 36 (5) e6627.
28. Liu L., Sim S. F., Lin S., Wan J., Zhang W., Li Q., and Peng C. (2021) Integrated structural and chemical analyses for HCl-supported hydrochar and their adsorption mechanisms for aqueous sulfachloropyridazine removal. J. Hazard. Mater., 417 1260.
29. Akpomie K. G., and Conradie J. (2020) Banana peel as a biosorbent for the decontamination of water pollutants. A review. Environ. Chem. Lett., 18 (4) 1085-1112.
30. Khan A., Naqvi H. J., Afzal S., Jabeen S., Iqbal M., and Riaz I. (2017) Efficiency enhancement of banana peel for waste water treatment through chemical adsorption: efficiency of banana peel for waste water treatment. Proc. Pak. Acad. Sci.: A, 54 (3) 329–335.
31. Maeda M., Takahara A., Kitano H., Yamaoka T., and Miura Y. (2019) Molecular soft-interface science, 1st Ed, Springer.
32. Shrestha B., Kour J., and Ghimire K. N. (2016) Adsorptive removal of heavy metals from aqueous solution with environmental friendly material—exhausted tea leaves. ACES., 6 (4) 525-540.
33. An Y., Zhang X., Wang X., Chen Z., and Wu X. (2018) Nano@ lignocellulose intercalated montmorillonite as adsorbent for effective Mn (II) removal from aqueous solution. Sci. Rep., 8 (1) 1-11.
34. Shibi I. G., and Anirudhan T. S. (2006) Polymer‐grafted banana (Musa paradisiaca) stalk as an adsorbent for the removal of lead (II) and cadmium (II) ions from aqueous solutions: kinetic and equilibrium studies. J. Chem. Technol. Biotechnol., 81 (3) 433-444.
35. Patescu R. E., Simonescu C. M., Busuioc L. T., Onose C., and Melinescu A. (2016) Simultaneous Removal of Lead (II), Nickel (II), Zinc (II) and Copper (II) from Aqueous Solutions by Nano-hydroxyapatite Synthesized by Microwave Field. REV.CHIM., 67 (10) 1899-1905.
36. Lingaraj C., and Singanan M. (2018) Removal of Divalent Cadmium Ions from Synthetic Wastewater Using Brown Mustard (Brassica Juncea) Leaves Biomass by Adsorption Process. Eur. J. Environ. Sci., 5 (1)1-6.
37. Zhou X., and Zhou X. (2014) The unit problem in the thermodynamic calculation of adsorption using the Langmuir equation. Chem. Eng. Commun., 201 (11) 1459-1467.
38. Jeppua P.J., and Clement P.T. (2012) A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects. J. Contam. Hydrol., 129 (130) 46–53.
39. Ayawei N., Ebelegi A. N., and Wankasi D. (2017) Modelling and interpretation of adsorption isotherms. J. Chem., 2017 1-11.
40. Ho Y. S. (2016) Comments on using of “pseudo-first-order model” in adsorption .Int. J. Biol. Macromol., 81 (88) 505-506.
41. Khamizov R. K. (2020) A pseudo-second order kinetic equation for sorption processes. Russ. J. Phys. Chem. A, 94 (1) 171-176.
42. Simonin J. P. (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. J. Chem. Eng., 300 254-263.