2,4,5-Trisubstituted imidazoles have many pharmaceutical properties and can be prepared via reaction of 1, 2-diketones with aldehydes in the presence of an acidic catalyst. In this work, we have prepared 2,4,5-trisubstituted imidazoles in the presence of trichloromelamine as a source of positive chlorine. Short reaction times, high yield, simplicity of operation and easy work-up are some advantages of this method.

In this paper, we establish an integrated mathematical production management model based on five parts insisted of finished goods production in production sites, inventory control of finished goods in production and distribution facilities, semi-finished goods production in producer’s facilities, inventory control of raw materials in production sites and Inventory control of semi-finished products. The main goal of developed model is to minimize total cost of company in the mentioned parts. Finally, the model is validated with 7 real-world case studies from auto-industry in one of the largest Iranian car producer company, Iran Khodro co and the empirical results are illustrated at the end of the paper.

The title compound 3-(4-hydroxy-3-methoxyphenyl)-7,7-dimethyl-7,8-dihydrocinnolin-5(6H)-one (3) was prepared via one-pot three component reaction of 2-(4-hydroxy-3-methoxyphenyl)-2-oxoacetaldehyde with dimedone in the presence of hydrazine hydrate and studied by the single crystal X-ray diffraction method. Its structure was also con?rmed by IR, 1H and 13C NMR spectroscopy. Compound 3 was crystallized in the monoclinic system, space group P21/c, a = 7.921(2) ?, b = 11.566(4) ?, c = 16.986(6) ?, B = 107.338(5)°, V = 1485.5(8) ?3, Z = 4, R1 = 0.0559 and wR2 = 0.1253. The crystal structure of 3 also shows a weak interaction between O3 and N2 atoms.

This study investigates the association between firm characteristics, corporate governance attributes and the level of corporate disclosure of listed firms in India. The research paper has been based on a sample of 60 firms listed in the Bombay Stock Exchange (BSE) / National Stock Exchange (NSE) during the study period from 2000-01 to 2009-10. The study has used the Standard & Poor (2008) model for measuring the level of corporate disclosure. To examine the association between explanatory variables and the level of corporate disclosure, multiple regression model has been used. The results suggest a positive relationship between board size, ratio of audit committee members to total board members, family control, CEO duality, firm size, profitability, liquidity and the extent of corporate disclosure. However, the degree of corporate disclosure is negatively related to board composition, leverage and age of the firm.

A new and simple method for the preconcentration and spectrophotometric determination of trace amounts of nickel was developed by cloud point extraction (CPE). In the proposed work, dimethylglyoxime (DMG) was used as the chelating agent and Triton X-114 was selected as a non-ionic surfactant for CPE. The parameters affecting the cloud point extraction including the pH of sample solution, concentration of the chelating agent and surfactant, equilibration temperature and time were optimized. Under the optimum conditions, the calibration graph was linear in the range of 10-150 ng mL-1 with a detection limit of 4 ng mL-1. The relative standard deviation for 9 replicates of 100 ng mL-1 Ni(II) was 1.04%. The interference effect of some anions and cations was studied. The method was applied to the determination of Ni(II) in water samples with satisfactory results.

Mode I and mode II stress intensity factors (SIFs) through the thickness of edge crack in semi circular bend (SCB) and center cracked circular disc (CCCD) specimens have been analyzed using three dimensional finite element analysis. The effect of the CCCD and SCB specimen thickness on the through-thickness variations of SIFs has been studied. For all mode of mixity, the peak value of mode I SIF is found at mid plane of SCB specimen and for thin CCCD specimen, while, this location is shifted to be near the free surface plane in thick CCCD specimen. The variation of mode II SIF in CCCD and SCB specimens have a similar trend.

The novel equivalent material concept, proposed originally by the author, was utilized together with the mean stress and the point stress failure concepts to predict the load-carrying capacity of O-notched ductile steel plates under pure tension. Unlike for V and U-notches, it was found that the point stress criterion combined with the equivalent material concept could estimate successfully the limited available experimental results reported in literature regarding four O-notched plates made of very ductile steel. By using the model, one may predict well the onset of tensile crack initiation in O-notched ductile components without requiring performing experiments or elastic-plastic analysis.

Semi-submersible drilling platforms are huge bulk structures for extracting the oil products from great depth of seas. For such bulk structures, the Morrison’s equations are no longer valid for determining the loads applied to the semi-submersible drilling platforms. The diffraction theory should be used for evaluating the hydrodynamic interactions between the platform and the sea waves. In this theory, the Laplace equation is solved by considering the boundary conditions of the diffraction theory. In this paper, after a brief description of the diffraction theory, the hydrodynamic interactions between the Iran’s Amirkabir semi-submersible drilling platform and the regular linear waves of Caspian Sea is investigated numerically using boundary element method in the ANSYS/AQWA software. The induced waves exciting forces and moments with different wave heading angles are estimated for six degrees of freedom relative to the waves frequencies using the diffraction theory. The performed hydrodynamic analysis is also validated with the previous works performed for Spar platforms.

In this paper, the stress intensity factors (SIFs) for an interfacial notch in a bi-material joint have been calculated using the experimental method of photoelasticity. A bi-material Brazilian disc specimen with a central interface notch was employed to determine the SIFs for different mode mixities. In this approach, SIFs were calculated experimentally for an Al/Polycarbonate bi-material Brazilian disc specimen and two different loading angles (i.e. modes I and II dominated loading conditions). The results of experimental approach were then compared with the numerical values of finite element method. Experimental results were in good consistency with the numerical values.

In today & apos; s world, many planning problems include a hierarchical decision structure with independent and often conflicting objectives. Therefore, the optimization of supply chains with hierarchical structure is essential. In this paper, we investigate a fuzzy multi-objective multi-products supply chain optimization problem in a bi-level structure with one level corresponding to a manufacturer planning problem, while the other to K distribution centers problem. In our model, customer demand and supply chain costs are considered uncertain and will be modeled with use of fuzzy sets. We first describe how different kinds of problems can be modeled as bi-level programming problems. Then, this fuzzy model is first converted into an equivalent crisp model by using ?-cut method in each level, and then by applying extended Kuhn–Tucker approach, we have a linear multi-objective programming problem. Fuzzy goal programming technique is applied to solve the multi-objective linear programming problem to obtain a set of Pareto-optimal solutions. Finally, a numerical example is illustrated to demonstrate the feasibility of the proposed approach.