From the perspective of carbon quota policy, we consider integrating carbon quota sharing contracts into the collaborative decision-making model of the photovoltaic industry chain and compare and explore the collaborative decision-making of the photovoltaic industry chain under decentralized decision-making and considering carbon quota sharing contracts. Research has found that carbon quota sharing contracts can effectively promote green innovation among the main body of the photovoltaic industry chain; In the case of carbon quota sharing contracts, the pricing between photovoltaic system suppliers and photovoltaic power plant enterprises is lower; Under the carbon quota sharing contract, the profits, and overall profits of each entity in the photovoltaic industry chain are better than the optimal profits under decentralized conditions.