Physical characteristics and Freundlich model of adsorption and desorption isotherm for fipronil in six types of Egyptian soil

Fouad, M.

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print) Quarterly Publication Volume 12 Issue 1 pp. 207-216 , 2023

Physical characteristics and Freundlich model of adsorption and desorption isotherm for fipronil in six types of Egyptian soil Pages 207-216 Download PDF

Authors: Mohamed Riad Fouad

DOI: 10.5267/j.ccl.2022.8.003

Keywords: Physical characteristics, Freundlich model, Sorption, Fipronil, Soil

Abstract: The soil type and temperature are considered important parameters that can influence the rates and equilibria of different environmental processes. Therefore, the adsorption and desorption isotherms of fipronil in clay loam, clay, sandy loam, sandy clay loam, sand and loamy sand soils at 25 and 50˚C was studied. The amount of fipronil adsorbed and desorbed by different soils was significantly influenced by the temperature. Adsorption was higher in clay loam, clay, sandy clay loam and sandy soil at 25°C, while sand soil and loamy sand soil at 50°C. The non-desorbed amount was greater at 25°C in different types of soil except for clay loam soil. The negative ΔG˚ indicated that the adsorption/desorption in different types of soil was spontaneous at different temperatures. The value of standard enthalpy change (ΔH˚) was positive in clay soil, sandy loam soil, sandy clay loam soil and loamy sand soil for adsorption and sandy loam soil, sand soil and loamy sand soil for desorption. Moreover, the standard entropy change (ΔS˚) was negative in soils for adsorption and desorption isotherms except clay loam soil. Adsorption and desorption isotherms trends as well as the values of the correlation coefficients indicated that the adsorption and desorption isotherms of fipronil in tested soils were fitted to the Freundlich model because the correlation coefficient is very close to 0.999.

How to cite this paper

 Fouad, M. (2023). Physical characteristics and Freundlich model of adsorption and desorption isotherm for fipronil in six types of Egyptian soil.Current Chemistry Letters, 12(1), 207-216.

Refrences

1. Masutti C. S. M., and Mermut A. R. (2007) Sorption of fipronil and its sulfide derivative by soils and goethite. Geoderma, 140 (1-2) 1-7.‏
2. Milonjić S. K. (2007) A consideration of the correct calculation of thermodynamic parameters of adsorption. J. Serbian Chem. Soc., 72 (12) 1363-1367.‏
3. Kumar M., and Philip L. (2006) Adsorption and desorption characteristics of hydrophobic pesticide endosulfan in four Indian soils. Chemosphere, 62 (7) 1064-1077.‏
4. El-Aswad A. F., Aly M. I., Fouad M. R., and Badawy M. E. (2019) Adsorption and thermodynamic parameters of chlorantraniliprole and dinotefuran on clay loam soil with difference in particle size and pH. J. Environ. Sci. Health B, 54 (6) 475-488.‏
5. Chen T., Da T., and Ma Y. (2021) Reasonable calculation of the thermodynamic parameters from adsorption equilibrium constant. J. Mol. Liq., 322 114980.‏
6. Cao W., Lyu Y., Yyu Y., Ye Q., She Y., and Wang J. (2013) Study on adsorption-desorption characteristics of butylene fipronil in soils. Acta Agric. Slov., 25 (1) 113-118.‏
7. Khuntong S., Sirivithayapakorn S., Pakkong P., and Soralump C. (2010) Adsorption kinetics of carbamate pesticide in rice field soil. Asian J. Environ. Sci., 3 20-28.
8. Sun Y., Clemens S. C., An Z., and Yu Z. (2006) Astronomical timescale and palaeoclimatic implication of stacked 3.6-Myr monsoon records from the Chinese Loess Plateau. Quat. Sci. Rev., 25 (1-2) 33-48.
9. Fouad M. R. (2017) Behaviour of some pesticides in soil. A Thesis Presented to the Graduate School Faculty of Agriculture, Alexandria University in Partial Fulfillment of the Requirements For the Degree of Master of Science.
10. Khan A. A., and Singh R. (1987) Adsorption thermodynamics of carbofuran on Sn (IV) arsenosilicate in H+, Na+ and Ca2+ forms. Colloids Surfaces, 24 (1) 33-42.
11. Biggar J., and Cheung M. (1973) Adsorption of picloram (4-amino-3, 5, 6-trichloropicolinic acid) on Panoche, Ephrata, and Palouse soils: a thermodynamic approach to the adsorption mechanism. Soil Sci. Soc. Am. J., 37 (6) 863-868.
12. Liu Y. (2009) Is the free energy change of adsorption correctly calculated?. J. Chem. Eng. Data, 54 (7) 1981-1985.‏
13. Fouad M. R., El-Aswad A. F., Badawy M. E. I., and Aly M. I. (2019) Adsorption isotherms modeling of herbicides bispyribac-sodium and metribuzin on two common Egyptian soil types. Int. J. Agric. Vet. Sci., 3 (2) 69-91.
14. Fouad M. R., and El-Aswad A. F. (2018) Competitive and non-competitive adsorption of atrazine and diuron on alluvial soil. Alex. Sci. Exch. J., 39 (July-September) 527-533.‏
15. Almalike L. B., Al-Najar A. A., and Kadhim Z. N. (2016) Physical characteristics of adsorption–desorption of Fipronil in the soil. Int. J. Eng. Res. Afr., 4 (2) 26-35.‏
16. Cleveland C. B. (1996) Mobility assessment of agrichemicals: current laboratory methodology and suggestions for future directions. Weed Technol., 10 (1) 157-168.
17. Southworth G. R., and Keller J. L. (1986) Hydrophobic sorption of polar organics by low organic carbon soils. Water Air Soil Pollut., 28 (3) 239-248.‏
18. Krishna K. R., and Philip L. (2008) Adsorption and desorption characteristics of lindane, carbofuran and methyl parathion on various Indian soils. J. Hazard. Mater., 160 (2-3) 559-567.
19. Singh R., Varshney K., and Rani S. (1985) Adsorption thermodynamics of carbofuran on sandy clay loam and silt loam soils. Ecotoxicol. Environ. Saf., 10 (3) 309-313.
20. Abate G., and Masini J. C. (2005) Sorption of atrazine, propazine, deethylatrazine, deisopropylatrazine and hydroxyatrazine onto organovermiculite. J. Braz. Chem. Soc., 16 936-943.
21. Ahmed A. A., Mohamed S. K., and Abdel-Raheem Sh. A. A. (2022) Assessment of the technological quality characters and chemical composition for some Egyptian Faba bean germplasm. Curr. Chem. Lett., Accepted Manuscript (DOI: 10.5267/j.ccl.2022.6.001).
22. Abdel-Raheem Sh. A. A., Kamal El-Dean A. M., Zaki R. M., Hassanien R., El-Sayed M. E. A., Sayed M., and Abd-Ella A. A. (2021) Synthesis and toxicological studies on distyryl-substituted heterocyclic insecticides. Eur. Chem. Bull., 10 (4) 225-229.
23. Yassin O., Ismail S., Gameh M., Khalil F., and Ahmed E. (2022) Evaluation of chemical composition of roots of three sugar beets varieties growing under different water deficit and harvesting dates in Upper Egypt. Curr. Chem. Lett., 11 (1) 1-10.‏
24. Abdelgalil A., Mustafa A. A., Ali S. A. M., and Yassin O. M. (2022) Effect of irrigation intervals and foliar spray of zinc and silicon treatments on maize growth and yield components of maize. ‏Curr. Chem. Lett., 11 (2) 219-226.‏
25. Yassin O. M., Ismail S., Ali M., Khalil F., and Ahmed E. (2021) Optimizing Roots and Sugar Yields and Water Use Efficiency of Different Sugar Beet Varieties Grown Under Upper Egypt Conditions Using Deficit Irrigation and Harvesting Dates. Egypt. J. Soil Sci., 61 (3) 367-372.
26. Abdelgali A., Mustafa A. A., Ali S. A. M., Yassin O. M. (2018) Irrigation intervals as a guide to surface irrigation scheduling of maize in Upper Egypt. J. Biol. Chem. Environ. Sci., 13 (2) 121-133.
27. Abdelgalil A., Mustafa A. A., Ali S. A. M., and Yassin O. M. (2022) Effect of different water deficit and foliar spray of zinc and silicon treatments of chemical composition of maize. ‏Curr. Chem. Lett., 11 (2) 191-198.
28. Saber A. F., Sayed M., Tolba M. S., Kamal A. M., Hassanien R., and Ahmed M. (2021) A Facile Method for Preparation and Evaluation of the Antimicrobial Efficiency of Various Heterocycles Containing Thieno[2,3-d]Pyrimidine. Synth. Commun., 51 (3) 398-409.
29. Ahmed M., Sayed M., Saber A. F., Hassanien R., Kamal El-Dean A. M., and Tolba M. S. (2020) Synthesis, Characterization, and Antimicrobial Activity of New Thienopyrimidine Derivatives. Polycycl. Aromat. Compd., Accepted Manuscript (DOI: 10.1080/10406638.2020.1852587).
30. Kamal El-Dean A. M., Zaki R. M., Radwan S. M., and Saber A. F. (2017) Synthesis, Reactions and Spectral Characterization of Novel Thienopyrazole Derivatives. Eur. Chem. Bull., 6 (12) 550–553.
31. Zaki R. M., Kamal El-Dean A. M., Radwan S. M., and Saber A. F. (2019) Efficient synthesis, reactions and spectral characterization of novel pyrazolo[4’,3’:4,5]thieno[3,2-d]pyrimidine derivatives and their related heterocycles. Heterocycl. Commun., 25 (1) 39–46.
32. Saber A. F., Zaki R. M., Kamal El-Dean A. M., and Radwan S. M. (2020) Synthesis, reactions and spectral characterization of some new biologically active compounds derived from thieno[2,3-c]pyrazole-5-carboxamide. J. Heterocyclic Chem., 57 (1) 238–247.
33. Zaki R. M., El-Dean A. M. K., Radwan S. M., and Saber A. F. (2018) A Convenient Synthesis, Reactions and Biological Activity of Some New 6H-Pyrazolo[4',3':4,5]thieno[3,2-d][1,2,3]triazine Compounds as Antibacterial, Anti-Fungal and Anti-Inflammatory Agents. J. Braz. Chem. Soc., 29 2482-2495.‏
34. Saber A. F., Kamal El‐Dean A. M., Redwan S. M., and Zaki R. M. (2020) Synthesis, spectroscopic characterization, and in vitro antimicrobial activity of fused pyrazolo[4′,3′:4,5]thieno[3, 2‐d]pyrimidine. J. Chin. Chem. Soc., 67 (7) 1239-1246.‏
35. Tolba M. S., Sayed M., Kamal El-Dean A. M., Hassanien R., Abdel-Raheem Sh. A. A., and Ahmed M. (2021) Design, synthesis and antimicrobial screening of some new thienopyrimidines. Org. Commun., 14 (4) 334-345.
36. Abdel-Raheem Sh. A. A., Kamal El-Dean A. M., Hassanien R., El-Sayed M. E. A., and Abd-Ella A. A. (2020) Synthesis and biological activity of 2-((3-Cyano-4,6-distyrylpyridin-2-yl)thio)acetamide and its cyclized form. Alger. j. biosciences, 01 (02) 046-050.
37. Abdel-Raheem Sh. A. A., Kamal El-Dean A. M., Abdul-Malik M. A., Hassanien R., El-Sayed M. E. A., Abd-Ella A. A., Zawam S. A., and Tolba M. S. (2022) Synthesis of new distyrylpyridine analogues bearing amide substructure as effective insecticidal agents. Curr. Chem. Lett., 11 (1) 23-28.
38. Bakhite E. A., Abd-Ella A. A., El-Sayed M. E. A., and Abdel-Raheem Sh. A. A. (2017) Pyridine derivatives as insecticides. Part 2: Synthesis of some piperidinium and morpholiniumcyanopyridinethiolates and their Insecticidal Activity. J. Saud. Chem. Soc., 21 (1) 95–104.
39. Kamal El-Dean A. M., Abd-Ella A. A., Hassanien R., El-Sayed M. E. A., Zaki R. M., and Abdel-Raheem Sh. A. A. (2019) Chemical design and toxicity evaluation of new pyrimidothienotetrahydroisoquinolines as potential insecticidal agents. Toxicol. Rep., 6 (2019) 100-104.
40. Abdel-Raheem Sh. A. A., Kamal El-Dean A. M., Hassanien R., El-Sayed M. E. A., and Abd-Ella A. A. (2021) Synthesis and characterization of some distyryl-derivatives for agricultural uses. Eur. Chem. Bull., 10 (1) 35-38.
41. Abdel-Raheem Sh. A. A., Kamal El-Dean A. M., Abdul-Malik M. A., Abd-Ella A. A., Al-Taifi E. A., Hassanien R., El-Sayed M. E. A., Mohamed S. K., Zawam S. A., and Bakhite E. A. (2021) A concise review on some synthetic routes and applications of pyridine scaffold compounds. Curr. Chem. Lett., 10 (4) 337-362.
42. Tolba M. S., Kamal El-Dean A. M., Ahmed M., Hassanien R., Sayed M., Zaki R. M., Mohamed S. K., Zawam S. A., and Abdel-Raheem Sh. A. A. (2022) Synthesis, reactions, and applications of pyrimidine derivatives. Curr. Chem. Lett., 11 (1) 121-138.
43. Abdelhafeez I. A., El-Tohamy S. A., Abdul-Malik M. A., Abdel-Raheem Sh. A. A., and El-Dars F. M. S. (2022) A review on green remediation techniques for hydrocarbons and heavy metals contaminated soil. Curr. Chem. Lett., 11 (1) 43-62.
44. Tolba M. S., Abdul-Malik M. A., Kamal El-Dean A. M., Geies A. A., Radwan Sh. M., Zaki R. M., Sayed M., Mohamed S. K., and Abdel-Raheem Sh. A. A. (2022) An overview on synthesis and reactions of coumarin based compounds. Curr. Chem. Lett., 11 (1) 29-42.
45. Abdelhamid A. A., Elsaghier A. M. M., Aref S. A., Gad M. A., Ahmed N. A., and Abdel-Raheem Sh. A. A. (2021) Preparation and biological activity evaluation of some benzoylthiourea and benzoylurea compounds. Curr. Chem. Lett., 10 (4) 371-376.
46. Elhady O. M., Mansour E. S., Elwassimy M. M., Zawam S. A., Drar A. M., and Abdel-Raheem Sh. A. A. (2022) Selective synthesis, characterization, and toxicological activity screening of some furan compounds as pesticidal agents. Curr. Chem. Lett., 11 (3) 285-290.
47. Kaid M., Ali A. E., Shamsan A. Q. S., Salem W. M., Younes S. M., Abdel-Raheem Sh. A. A., and Abdul-Malik M. A. (2022) Efficiency of maturation oxidation ponds as a post-treatment technique of wastewater. Curr. Chem. Lett., Accepted Manuscript (DOI: 10.5267/j.ccl.2022.4.005).
48. Mohamed S. K., Mague J. T., Akkurt M., Alfayomy A. M., Abou Seri S. M., Abdel-Raheem Sh. A. A., and Abdul-Malik M. A. (2022) Crystal structure and Hirshfeld surface analysis of ethyl (3E)-5-(4-chlorophenyl)-3-{[(4-chlorophenyl)formamido]imino}-7-methyl-2H,3H,5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate. Acta Cryst., Accepted Manuscript (DOI: 10.1107/S205698902200603X).
49. Abd-Ella A. A., Metwally S. A., Abdul-Malik M. A., El-Ossaily Y. A., Abd Elrazek F. M., Aref S. A., Naffea Y. A., and Abdel-Raheem Sh. A. A. (2022) A review on recent advances for the synthesis of bioactive pyrazolinone and pyrazolidinedione derivatives. Curr. Chem. Lett., 11 (2) 157-172.